Beilstein J. Org. Chem.2017,13, 2466–2472, doi:10.3762/bjoc.13.243
polymerizations was well-controlled by applying optimal potential values during preparative electrolysis to prevent the possibility of intermolecular coupling of the growing polymer arms. This appears to be the first report using on-demandseATRP for the synthesis of QC-(PtBA-Br)5 pseudo-star polymers. The
naturally-derived macromolecules showed narrow MWDs (Đ = 1.08–1.11). 1H NMR spectral results confirm the formation of quercetin-based polymers. These new flavonoid-based polymer materials may find applications as antifouling coatings and drug delivery systems.
Keywords: flavonoids; on-demandseATRP
',5,6-pentahydroxyflavone-based core with 2-bromoisobutyryl bromide as initiation molecule, and grafting of the PtBA arms of the flavonoid-based moiety by facile seATRP technique. To demonstrate the possibility of temporal control, on-demandseATRP was carried out utilizing multiple-step potential
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Graphical Abstract
Figure 1: 1H NMR analysis of QC-Br5 (Mn = 1,050, Ð = 1.11) after purification (in CDCl3).